Aero formulas: Difference between revisions
From NPrize
Jump to navigationJump to search
density |
→List of equations: adding dH(S,p) |
||
Line 139: | Line 139: | ||
|- | |- | ||
|style="background:white"| {{SERVER}}/images/formulas_mirror/entropy_dueqtdsmpdv.png | |style="background:white"| {{SERVER}}/images/formulas_mirror/entropy_dueqtdsmpdv.png | ||
|[https://en.wikipedia.org/wiki/Entropy | |[https://en.wikipedia.org/wiki/Internal_energy Internal energy] change related to [https://en.wikipedia.org/wiki/Entropy entropy] | ||
|Internal energy related to entropy variation for a closed system in thermal equilibrium ([https://en.wikipedia.org/wiki/Fundamental_thermodynamic_relation fundamental thermodynamic relation]). | |Internal energy related to entropy variation for a closed system in thermal equilibrium ([https://en.wikipedia.org/wiki/Fundamental_thermodynamic_relation fundamental thermodynamic relation]). | ||
|- | |||
|style="background:white"| {{SERVER}}/images/formulas_mirror/dheqtds.png | |||
|[https://en.wikipedia.org/wiki/Enthalpy Enthalpy] change | |||
|Enthalpy change depending on entropy and pressure changes, equation created from the mix of the basic ones above. | |||
|- | |- | ||
|ΔS<sub>universe</sub> = ΔS<sub>surroundings</sub> + ΔS<sub>system</sub> | |ΔS<sub>universe</sub> = ΔS<sub>surroundings</sub> + ΔS<sub>system</sub> |
Revision as of 19:43, 1 May 2012
The List of elementary physics formulae on wikipedia is useful.
List of variables
Variable | Meaning | Unit (SI) |
---|---|---|
γ (gamma) | Surface tension or Heat capacity ratio (adiabatic process in thermodynamics) | N.m-1 (Newton per meter) |
μ (mu) or η (eta) | Viscosity | Pa·s (Pascal second) or P (Poise, 1 Poise is 0.1 Pa.s) |
ρ (rho) | Density | kg.m-3 (kg per cubic meter) |
C, Cp, CV | Heat capacity, general, at constant pressure, at constant volume. | J.K-1 (Joule per Kelvin) |
G | Gibbs free energy | J (Joule) |
H | Enthalpy: total energy of a thermodynamic system. | J (Joule) |
ΔHvap or L | Vaporization heat or Latent heat of vaporization: energy required to vaporize a mole of liquid at a given temperature. | J.mol-1 (Joule per mole) |
M | Mach number | no unit |
Q | Amount of Heat | J (Joule) |
T | Temperature. T0 or Tt is the stagnation temperature. | K (Kelvin) |
S | Entropy | J.K-1 (Joule per Kelvin) |
U | Internal energy of a system (see first law of Thermodynamics below) | J (Joule) |
V | Volume | m3 (cubic meter) |
W | Work: mechanical constraints on the system. | J (Joule) |
a | Speed of sound in medium (used to calculate Mach number) | m.s-1 |
c | Velocity of a flow in thermodynamics, also noted V; generally noted u in fluid dynamics. | m.s-1 |
n | Quantity of matter | mol (mole) |
p | Pressure. pt is the stagnation pressure. | Pa (Pascal) |
List of constants
Constant | Meaning | Value | Unit (SI) |
---|---|---|---|
NA or N | Avogadro constant, number of atoms or molecules in a mole. | 6.02214129.1023 | mol-1 |
R | ideal gas constant | 8.3144621 | J.K−1.mol−1 |
kB or k | Boltzmann constant, gas constant R divided by Avogadro number. | 1.3806488.10-23 | J.K-1 |
List of equations
Equation | Name | Meaning |
---|---|---|
Ideal gas equation | Relation between properties of an ideal gas (state equation). k is kB. | |
Clausius-Clapeyron relation | Relation between the pressure, latent heat of vaporization and temperature of a vapour at two temperatures (approximation, at low temperatures). | |
Heat at state change for an ideal gas. | The heat required to change the state of a some matter, L being the latent heat. Delta H equals Q only when pressure is constant (isobaric). | |
First law of thermodynamics | Variations of internal energy of a system between two states is the sum of the received heat and work (minus the given work). | |
Enthalpy | Total amount of energy of a system, defined as the sum of the internal energy U of the system and pressure * volume at the boundary of the system and its environment. | |
Work of gas expansion. | Work done by expanding an ideal gas. | |
Internal energy change related to entropy | Internal energy related to entropy variation for a closed system in thermal equilibrium (fundamental thermodynamic relation). | |
Enthalpy change | Enthalpy change depending on entropy and pressure changes, equation created from the mix of the basic ones above. | |
ΔSuniverse = ΔSsurroundings + ΔSsystem | Entropy variation as a whole. | Entropy variation of a system is generally compensated by the inverse variation of the surroundings, not including losses. |
Second law of thermodynamics | A change in the entropy of a system is the infinitesimal transfer of heat to a closed system driving a reversible process, divided by the equilibrium temperature of the system. | |
Gibbs free energy / Free enthalpy | Useful work obtainable from a system at isobaric and isothermal conditions. Since H is U + pV, it can be replaced in the equation, making G = H - TS. | |
Gibbs free energy variation. | If ΔG < 0, the system's transformation can be spontaneous, if ΔG = 0 the transformation is inversible and the system is in an equilibrium state, if ΔG > 0 it can't be spontaneous. | |
Density of an ideal gas. | M is molar mass. This means that the density of an ideal gas can be doubled by doubling the pressure, or by halving the absolute temperature. |