Aero formulas: Difference between revisions
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basic entropy |
more entropy and gibbs energy |
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|[https://en.wikipedia.org/wiki/Entropy Entropy] | |[https://en.wikipedia.org/wiki/Entropy Entropy] | ||
|Internal energy related to entropy variation for a closed system in thermal equilibrium ([https://en.wikipedia.org/wiki/Fundamental_thermodynamic_relation fundamental thermodynamic relation]). | |Internal energy related to entropy variation for a closed system in thermal equilibrium ([https://en.wikipedia.org/wiki/Fundamental_thermodynamic_relation fundamental thermodynamic relation]). | ||
|- | |||
|ΔS<sub>universe</sub> = ΔS<sub>surroundings</sub> + ΔS<sub>system</sub> | |||
|Entropy variation as a whole. | |||
|Entropy variation of a system is generally compensated by the inverse variation of the surroundings not including losses. | |||
|- | |||
|style="background:white"| {{SERVER}}/images/formulas_mirror/gibbs.png | |||
|[https://en.wikipedia.org/wiki/Gibbs_free_energy Gibbs free energy] / Free enthalpy | |||
|Useful work obtainable from a system at isobaric and isothermal conditions. | |||
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Revision as of 02:44, 10 April 2012
The List of elementary physics formulae on wikipedia is useful.
List of variables
Variable | Meaning | Unit (SI) |
---|---|---|
γ (gamma) | Surface tension | N.m-1 (Newton per meter) |
μ (mu) or η (eta) | Viscosity | Pa·s (Pascal second) or P (Poise, 1 Poise is 0.1 Pa.s) |
H | Enthalpy: total energy of a thermodynamic system. | J (Joule) |
or L | Vaporization heat or Latent heat of vaporization: energy required to vaporize a mole of liquid at a given temperature. | J.mol-1 (Joule per mole) |
Q | Amount of Heat | J (Joule) |
T | Temperature | K (Kelvin) |
S | Entropy | J.K-1 (Joule per Kelvin) |
U | Internal energy of a system (see first law of Thermodynamics below) | J (Joule) |
V | Volume | m3 (cubic meter) |
W | Work: mechanical constraints on the system. | J (Joule) |
n | Quantity of matter | mol (mole) |
p | Pressure | Pa (Pascal) |
List of constants
Constant | Meaning | Value | Unit (SI) |
---|---|---|---|
NA or N | Avogadro constant, number of atoms or molecules in a mole. | 6.02214129.1023 | mol-1 |
R | ideal gas constant | 8.3144621 | J.K−1.mol−1 |
kB or k | Boltzmann constant, gas constant R divided by Avogadro number. | 1.3806488.10-23 | J.K-1 |
List of equations
Equation | Name | Meaning |
---|---|---|
Ideal gas equation | Relation between properties of an ideal gas (state equation). k is kB. | |
Clausius-Clapeyron relation | Relation between the pressure, latent heat of vaporization and temperature of a vapour at two temperatures (approximation, at low temperatures). | |
Definition of Heat for an ideal gas. | The heat required to change the temperature of a system from an initial temperature T0, to a final temperature, Tf. | |
Heat at state change for an ideal gas. | The heat required to change the state of a some matter, L being the latent heat. Delta H equals Q only when pressure is constant (isobaric). | |
First law of Thermodynamics | Variations of internal energy of a system between two states is the sum of the received heat and work (minus the given work). | |
Enthalpy | Total amount of energy of a system, defined as the sum of the internal energy U and pressure * volume. | |
Work of gas expansion. | Work done by expanding an ideal gas. | |
Entropy | Internal energy related to entropy variation for a closed system in thermal equilibrium (fundamental thermodynamic relation). | |
ΔSuniverse = ΔSsurroundings + ΔSsystem | Entropy variation as a whole. | Entropy variation of a system is generally compensated by the inverse variation of the surroundings not including losses. |
Gibbs free energy / Free enthalpy | Useful work obtainable from a system at isobaric and isothermal conditions. |